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class="caseCmenu"> <h3>多效蒸發(fā)技術(shù)在高鹽廢水處理中的應用</h3> <span id="dhr93v9tpzzz" class="casemfx"> 所屬分類(lèi)：行業(yè)動(dòng)態(tài) 發(fā)布時(shí)間： 2021-06-29 作者： <div id="dhr93v9tpzzz" class="bdsharebuttonbox"> <i> 分享到：</i> <a href="#" class="bds_more" data-cmd="more"></a> <a href="#" class="bds_sqq" data-cmd="sqq" title="分享到QQ好友"></a> <a href="#" class="bds_weixin" data-cmd="weixin" title="分享到微信"></a> </div> <a href="#" class="scan" title="二維碼分享">二維碼分享 <div class="dhr93v9tpzzz" id="qrcode" style="display: none"> </div> </a> </span> </div> <div id="dhr93v9tpzzz" class="caseContainer"> <span style="font-size:16px;">多效蒸發(fā)處理器主要用來(lái)處理高濃度、高色度、高含鹽量的工業(yè)廢水。同時(shí)，回收廢水處理過(guò)程中產(chǎn)生的附產(chǎn)品。蒸汽耗量低、蒸發(fā)溫度低、濃縮比大、更合理、更節能、更高效。今天就為大家介紹多效蒸發(fā)器在廢水處理中的應用！</span><br /> <br /> <span style="font-size:16px;">工業(yè)廢水分類(lèi)通常有以下三種</span><br /> <br /> <span style="font-size:16px;">按工業(yè)廢水中所含主要污染物的化學(xué)性質(zhì)分類(lèi)，含無(wú)機污染物為主的為無(wú)機廢水，含有機污染物為主的為有機廢水。例如電鍍廢水和礦物加工過(guò)程的廢水，是無(wú)機廢水；食品或石油加工過(guò)程的廢水，是有機廢水。 </span><br /> <br /> <span style="font-size:16px;">按工業(yè)企業(yè)的產(chǎn)品和加工對象分類(lèi)，如冶金廢水、造紙廢水、煉焦煤氣廢水、金屬酸洗廢水、化學(xué)肥料廢水、紡織印染廢水、染料廢水、制革廢水、農藥廢水、電站廢水等。</span><br /> <br /> <span style="font-size:16px;">按廢水中所含污染物的主要成分分類(lèi)，如酸性廢水、堿性廢水、含氰廢水、含鉻廢水、含鎘廢水、含汞廢水、含酚廢水、含醛廢水、含油廢水、含硫廢水、含有機磷廢水和放射性廢水等。</span><br /> <br /> <span style="font-size:16px;">前兩種分類(lèi)法不涉及廢水中所含污染物的主要成分，也不能表明廢水的危害性。第三種分類(lèi)法，明確地指出廢水中主要污染物的成分，能表明廢水一定的危害性。</span><br /> <br /> <p style="text-align:center;"> <span style="font-size:16px;"><img src="/upload/210629/996402652076e749ad7e53eff7928af0.jpg" alt="" width="800" height="1067" title="" align="" /><br /> </span> </p> <p> <span style="font-size:16px;"><br /> </span> </p> <p> <span style="font-size:16px;">多效蒸發(fā)的技術(shù)特點(diǎn)</span> </p> <br /> <span style="font-size:16px;">多效蒸發(fā)是使用海水淡化技術(shù)，現今已經(jīng)發(fā)展成為較為成熟的廢水蒸發(fā)技術(shù)，解決了結垢嚴重的問(wèn)題，逐步應用于高含鹽水處理方向。</span><br /> <br /> <span style="font-size:16px;">多效主要有如下幾個(gè)方面的技術(shù)特點(diǎn)：</span><br /> <br /> <span style="font-size:16px;">多效蒸發(fā)的傳熱過(guò)程是沸騰和冷凝換熱，是雙側相變傳熱，因此傳熱系數很高。對于相同的溫度范圍，多效蒸發(fā)所用的傳熱面積要比多級閃蒸少。</span><br /> <br /> <span style="font-size:16px;">多效蒸發(fā)的動(dòng)力消耗少。由于多級閃蒸產(chǎn)生淡水依賴(lài)的是含鹽水吸收的顯熱，而潛熱遠大于顯熱，因此生產(chǎn)同樣多的淡水，多級閃蒸需要的循環(huán)量比多效蒸發(fā)大出很多，所以多級閃蒸需要更多的動(dòng)力消耗。</span><br /> <br /> <span style="font-size:16px;">多效蒸發(fā)的操作彈性很大，負荷范圍從110%到40%，皆可正常操作，而且不會(huì )使造水比下降。</span><br /> <br /> <span style="font-size:16px;">含鹽廢水的工藝流程</span><br /> <br /> <span style="font-size:16px;">含鹽水冷凝器中預熱、脫氣，而后被分成兩股物流。一股作為冷卻水排回大海，另一股作為蒸餾過(guò)程的進(jìn)料。</span><br /> <br /> <span style="font-size:16px;">進(jìn)料含鹽水加入阻垢劑后被引入到蒸發(fā)器的后幾效中。料液經(jīng)噴嘴被均勻分布到蒸發(fā)器的頂排管上，然后沿頂排管以薄膜形式向下流動(dòng)，部分水吸收管內冷凝蒸汽的潛熱而蒸發(fā)。</span><br /> <br /> <span style="font-size:16px;">二次蒸汽在下一效中冷凝成產(chǎn)品水，剩余料液由泵輸送到蒸發(fā)器的下一個(gè)效組中，該組的操作溫度比上一組略高，在新的效組中重復噴淋、蒸發(fā)、冷凝過(guò)程。剩余的料液由泵往高溫效組輸送。</span><br /> <br /> <span style="font-size:16px;">冷凝液返回蒸汽發(fā)生器，其余效的冷凝液進(jìn)入產(chǎn)品水罐，各效產(chǎn)品水罐相連。由于各效壓力不同使產(chǎn)品水閃蒸，并將熱量帶回蒸發(fā)器。這樣，產(chǎn)品水呈階梯狀流動(dòng)并被逐級閃蒸冷卻，回收的熱量可提高系統的總效率。被冷卻的產(chǎn)品水由產(chǎn)品水泵輸送到產(chǎn)品水儲罐。這樣生產(chǎn)出來(lái)的產(chǎn)品水是平均含鹽量小于5mg/1的純水。</span><br /> <br /> <span style="font-size:16px;">濃鹽水效呈階梯狀流入一系列的濃鹽水閃蒸罐中，過(guò)熱的濃鹽水被閃蒸以回收其熱量。經(jīng)過(guò)閃蒸冷卻之后的濃鹽水經(jīng)濃鹽水泵排回大海。</span><br /> <br /> <span style="font-size:16px;">不凝氣在冷凝器富集，由真空泵抽出。</span><br /> <br /> <span style="font-size:16px;">低溫多效蒸發(fā)的技術(shù)優(yōu)勢</span><br /> <p> <br /> </p> <p style="text-align:center;"> <img src="/upload/210629/bfa8cd5a5827a33446b76858ac921104.jpg" alt="" width="800" height="1067" title="" align="" /> </p> <p> <span style="font-size:16px;"><br /> </span> </p> <p> <span style="font-size:16px;">從其上述原理可以看出，低溫多效蒸發(fā)的技術(shù)優(yōu)勢體現在如下幾個(gè)方面：</span> </p> <br /> <span style="font-size:16px;">由于操作溫度低，可充分利用電廠(chǎng)和化工廠(chǎng)的低溫廢熱，對低溫多效蒸發(fā)技術(shù)而言，50℃-70℃的低品位蒸汽均可作為理想的熱源，可大大減輕抽取背壓蒸汽對電廠(chǎng)發(fā)電的影響。</span><br /> <br /> <span style="font-size:16px;">進(jìn)料含鹽水的預處理更為簡(jiǎn)單。系統低溫操作帶來(lái)的另一大好處是大大的簡(jiǎn)化了含鹽水的預處理過(guò)程。含鹽水進(jìn)入低溫多效裝置之前只需經(jīng)過(guò)篩網(wǎng)過(guò)濾和加入少量阻垢劑就行，而不象多級閃蒸那樣必須進(jìn)行加酸脫氣處理。</span><br /> <br /> <span style="font-size:16px;">系統的操作彈性大。在高峰期，該淡化系統可以提供設計值110%的產(chǎn)品水；而在低谷期，該淡化系統可以穩定地提供額定值40%的產(chǎn)品水。</span><br /> <br /> <span style="font-size:16px;">系統的動(dòng)力消耗小。低溫多效系統用于輸送液體的動(dòng)力消耗很低，只有0.9- 1.2kWh/m3左右。如此可以大大的降低淡化水的制水成本，這一點(diǎn)對于電價(jià)較高的地區尤為重要。</span><br /> <br /> <span style="font-size:16px;">系統的熱效率高。30余度的溫差即可安排12以上的傳熱效數，從而達到10左右的造水比。</span><br /> <br /> <span style="font-size:16px;">系統的操作安全可靠。在低溫多效系統中，發(fā)生的是管內蒸汽冷凝而管外液膜蒸發(fā)，即使傳熱管發(fā)生了腐蝕穿孔而泄漏，由于汽側壓力大于液膜側壓力，濃鹽水不會(huì )流到產(chǎn)品水中，充其量只會(huì )產(chǎn)生蒸汽的少量泄漏而影響造水量。</span><br /> <br /> <span style="font-size:16px;">煉化企業(yè)有大量富裕的低溫余熱待利用，經(jīng)過(guò)低溫多效蒸發(fā)技術(shù)處理后的淡水可回用至多個(gè)工藝環(huán)節，如循環(huán)水補水等，實(shí)現污水的資源化利用的同時(shí)，實(shí)現了低溫余熱的高效利用。</span><br /> <br /> <span style="font-size:16px;">因此，將低溫多效蒸發(fā)技術(shù)引入煉化企業(yè)水處理行業(yè)，利用其高造水比、處理水質(zhì)好等優(yōu)點(diǎn)，可以實(shí)現低溫余熱利用和煉化污水深度處理的有機結合，并解決煉化污水中高含鹽污水脫鹽難、能耗高等問(wèn)題。</span><br /> <br /> <span style="font-size:16px;">如低溫熱利用技術(shù)對比表所示，較常規熱泵技術(shù)和多級閃蒸技術(shù)，低溫多效蒸發(fā)在熱利用率、技術(shù)工藝耦合污水處理等方面具有明顯優(yōu)勢，代表了相關(guān)技術(shù)領(lǐng)域的發(fā)展方向，是開(kāi)展余熱利用和污水處理耦合技術(shù)的重點(diǎn)方向。</span><br /> <br /> <span style="font-size:16px;">多效蒸發(fā)的工藝模式</span><br /> <br /> <span style="font-size:16px;">多效蒸發(fā)工藝有以下幾種工藝模式：</span><br /> <br /> <span style="font-size:16px;">順流工藝流程</span><br /> <br /> <span style="font-size:16px;">溶液和蒸汽的流向相同，依靠效間壓差，自流入（濃縮過(guò)程中要是有固體產(chǎn)生或溶液粘度較大就需要添加過(guò)料泵）下一效進(jìn)行處理，完成液自末效用泵抽出。</span><br /> <br /> <p style="text-align:center;"> <span style="font-size:16px;"><img src="/upload/210629/5ef457f6ce81fcb80876206be737ee0f.jpg" alt="" width="800" height="1067" title="" align="" /><br /> </span> </p> <p> <span style="font-size:16px;">后一效的壓力低，溶液的沸點(diǎn)也相對較低，故溶液從前一效進(jìn)入后一效時(shí)會(huì )因過(guò)熱而自行蒸發(fā)，稱(chēng)為閃蒸。因而后一效有可能比前效產(chǎn)生較多的二次蒸汽，但因為后效的濃度比前效高，而操作溫度又較低，所以后一效的傳熱系數比前一效要低。</span> </p> <br /> <span style="font-size:16px;">平流加料工藝流程</span><br /> <span style="font-size:16px;">各效都加入料液，又都引出完成液。此流程用于飽和溶液的蒸發(fā)（或溶液濃度較高）。各效都有晶體析出，可及時(shí)分離晶體。此法還可用于同時(shí)濃縮兩種或多種水溶液。</span><br /> <br /> <span style="font-size:16px;">選擇順流工藝的原因：污水進(jìn)水料液粘稠度低，不含有大量低沸點(diǎn)的物質(zhì)，不需要選擇逆流模式先冷凝，且不影響傳熱系數。其次，污水進(jìn)水鹽濃度并不高，只有在極其高濃度時(shí)，選擇并流加料模式。</span><br /> </div> <div id="dhr93v9tpzzz" class="caseTab"> <ul> <li id="dhr93v9tpzzz" class="col-xs-6 col-sm-6 col-md-6"> <a href="/question/650.html">這是對脫氮除磷核心問(wèn)題最強的總結，解決了你99%的問(wèn)題</a> </li> <li id="dhr93v9tpzzz" class="col-xs-6 col-sm-6 col-md-6"> <a 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